THE EFFECT OF VARIABLE BINDERS ON MECHANICAL AND FIBER/MATRIX INTERPHASE PROPERTIES OF PEEK/AS4 COMPOSITE SYSTEMS

Hans DeSmidt and Dr. Kenneth L. Reifsnider
National Science Foundation and Technology Center:
High Performance Polymeric Adhesive and Composites, and
Engineering Science and Mechanics Department
Virginia Polytechnic Institute and State University
Blacksburg, Virginia

ABSTRACT

It is apparent from experimental data that the mechanical properties of PEEK/AS4 composite systems manufactured by suspension prepregging are greatly influenced by the chemical binder used. Unidirectional composites manufactured with a PAA TMA+ binder dissolved in an aqueous suspension of PEEK particles fail plastically in uniaxial tension. Unidirectional composites manufactured with a PAA NH4+ fail elasticly in uniaxial tension. Both systems have similar tensile elastic moduli prior to fiber/matrix interfacial debonding. Systems manufactured with PAA NH4+ binder have a 30% greater failure strength than composites made with PAA TMA+ binder. Both systems have interfacial efficiencies of around 76%. Unlike the interfacial efficiency, the interfacial shear strength values for the PAA NH4+ binder systems is much larger than the PAA TMA+ system.

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